Skip to main content
SpringerLink
Log in

Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium cluster ”Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}”

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The structure of the previously synthesized triosmium cluster was revised. The structure Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph} suggested earlier was not confirmed. The cluster has the composition Os3(μ-H)2(CO)7(μ-C5H4N){μ3-Ph2PCH2P(C6H4)Ph} and contains the ortho-metalated pyridine ligand. The X-ray diffraction study of the complex Os3(μ-H)2(CO)7(μ-MeC5H3N){μ3-Ph2PCH2P(C6H4)Ph} containing the ortho-metalated 4-methylpyridine ligand made it possible to distinguish between the C and N atoms of the pyridine ligands in the resulting triosmium clusters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. A. A. Koridze, V. I. Zdanovich, V. Yu. Lagunova, I. I. Petukhova, F. M. Dolgushin, Z. A. Starikova, M. G. Ezernitskaya, P. V. Petrovskii, Izv. Akad. Nauk, Ser. Khim., 2002, 807 [Russ. Chem. Bull., Int. Ed., 2002, 51, 876].

    Google Scholar 

  2. A. A. Koridze, S. A. Kuklin, P. V. Petrovskii, F. M. Dolgushin, M. G. Ezernitskaya, Izv. Akad. Nauk, Ser. Khim., 2002, 328 [Russ. Chem. Bull., Int. Ed., 2002, 51, 350].

    Google Scholar 

  3. C. W. Bradford, R. S. Nyholm, J. Chem. Soc., Dalton Trans. 1973, 529.

  4. M. I. Bruce, B. W. Skelton, A. H. White, N. N. Zaitseva, Inorg. Chem. Commun., 1999, 2, 17.

    Article  CAS  Google Scholar 

  5. J. A. Clucas, D. F. Forster, M. M. Harding, A. K. Smith, J. Chem. Soc., Chem. Commun., 1984, 949.

  6. J. A. Clucas, P. A. Dolby, M. M. Harding, A. K. Smith, J. Chem. Soc., Chem. Commun., 1987, 1829.

  7. SHELXTL v. 5.10, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA, 1998.

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Koridze, S. A. Kuklin, N. A. Shtelzer, P. V. Petrovskii, F. M. Dolgushin & M. G. Ezernitskaya

Authors
  1. A. A. Koridze
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Kuklin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Shtelzer
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. V. Petrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. M. Dolgushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. G. Ezernitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Koridze.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2152–2155, October, 2008.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Koridze, A.A., Kuklin, S.A., Shtelzer, N.A. et al. Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium cluster ”Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}”. Russ Chem Bull 57, 2194–2197 (2008). https://doi.org/10.1007/s11172-008-0299-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-008-0299-x

Key words

Search

Navigation